Properties and Overview of Carbon
Overview:
Carbon (C) is a fundamental chemical element with the atomic number 6 and the C symbol on the periodic table. It is the fourth most abundant element in the universe by mass and is a cornerstone of organic chemistry, making it essential to life as we know it. Carbon's versatility arises from its ability to form stable bonds with many elements, including itself, leading to an extraordinary variety of compounds. This property is the foundation of the vast diversity of organic molecules that make up living organisms and countless synthetic materials. Physically, Carbon exhibits several allotropes, each with distinct properties. The most well-known allotropes are graphite, diamond, and amorphous Carbon. Graphite is a soft, black, and slippery material that is an excellent conductor of electricity. It has a layered structure, with each layer consisting of hexagonally arranged Carbon atoms bonded strongly within the layer but weakly between layers, allowing them to slide over each other easily. This property makes graphite useful as a lubricant and in applications like pencil leads. Diamond, on the other hand, is the hardest known natural material. It has a crystal lattice structure where each Carbon atom is tetrahedrally bonded to four other Carbon atoms, resulting in its remarkable hardness and high thermal conductivity. Amorphous Carbon lacks a crystalline structure and is found in substances like coal, charcoal, and soot. Each form of Carbon has unique physical properties that make it suitable for various applications, from industrial uses to jewelry.
Chemically, Carbon is highly versatile due to its ability to form four covalent bonds with other atoms. This tetravalency allows Carbon to create a vast array of organic compounds, including hydroCarbons, alcohols, acids, and polymers. Carbon can form single, double, and triple bonds, leading to various molecular geometries and complex structures. Carbon's ability to form stable chains and rings of atoms is the basis for the complexity and diversity of organic chemistry. This property is crucial for biomolecules such as DNA, proteins, carbohydrates, and lipids, essential to life.
When dealing with certain forms of Carbon and its compounds, it's important to exercise caution. For instance, Carbon monoxide (CO) is a highly toxic gas that binds to hemoglobin in the blood, preventing the transport of oxygen and leading to potentially fatal poisoning if inhaled in significant quantities. Carbon black, a fine particulate form of Carbon, can be harmful if inhaled over long periods, potentially leading to respiratory issues. Additionally, diamond dust, if inhaled or introduced into the eyes, can cause physical harm. Therefore, while elemental Carbon in common forms like graphite or diamond is safe to handle, it's crucial to be aware of the potential risks and take necessary safety precautions when dealing with certain Carbon compounds and particulate forms.
Carbon dioxide (CO2) and Carbon monoxide (CO) are essential Carbon-containing compounds. CO2 is a colorless gas produced by the combustion of Carbon-containing fuels and is a critical component of the Earth's Carbon cycle. It is used by plants in photosynthesis to produce oxygen and organic matter, which is the foundation of most food chains. However, excessive CO2 emissions from human activities, notably burning fossil fuels, are a significant contributor to global climate change due to its role as a greenhouse gas. As mentioned earlier, Carbon monoxide is a poisonous gas that can result from incomplete combustion and is dangerous even at low concentrations.
Production:
The production of Carbon varies depending on its form. For instance, graphite, one of the most common forms of Carbon, is typically obtained through mining natural graphite deposits, which are then processed to purify the material. Synthetic graphite can also be produced by heating petroleum coke, a byproduct of oil refining, to high temperatures in an electric arc furnace. Diamond, another form of Carbon, can be mined from natural deposits or produced synthetically through high-pressure, high-temperature (HPHT) processes or chemical vapor deposition (CVD). Activated Carbon, a highly porous form of Carbon used in filtration and purification, is produced by treating Carbon-rich materials like wood, coal, or coconut shells with high temperatures and chemicals to create a network of fine pores.
Applications:
Carbon has various applications across various industries due to its diverse physical and chemical properties. Carbon is used in electrodes and batteries and as a lubricant in graphite form. It is also used in steel production, where it plays a crucial role in controlling the hardness and strength of the alloy. Carbon fibers, which are lightweight yet extremely strong, are used in advanced composites for the aerospace, automotive, and sporting goods industries. Natural and synthetic diamonds are prized for their hardness and optical properties, making them ideal for cutting tools and jewelry. Activated Carbon, with its vast surface area, is widely used in water and air purification, as well as in medical applications to treat poisonings and overdoses through adsorption of toxins.
In the realm of nanotechnology, Carbon nanotubes and graphene, both allotropes of Carbon, have garnered significant attention. Carbon nanotubes are cylindrical molecules with extraordinary strength, electrical conductivity, and thermal conductivity, making them promising materials for a wide range of applications, including in electronics, materials science, and medicine. Similarly, graphene, a single layer of Carbon atoms arranged in a hexagonal lattice, is renowned for its exceptional strength, flexibility, and electrical conductivity. It is being explored for use in electronics, energy storage, and composite materials, offering exciting possibilities for the future.
Summary:
Carbon is a unique and indispensable element with a broad range of forms and applications. Its physical and chemical versatility allows it to play a crucial role in both the natural world and human industry. While generally safe in its common forms, certain Carbon compounds and allotropes require careful handling due to their potential health and environmental risks. As an essential building block of life and a critical material in modern technology, Carbon continues to be a focus of scientific research and industrial innovation, underscoring its significance and relevance.
See a comprehensive list of atomic, electrical, mechanical, physical and thermal properties for carbon below:
Atomic Structure of Carbon
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Atomic Properties of Carbon
Atomic Property (Units) | Value |
---|---|
Carbon Atomic Electron Configuration | [He] 2s22p2 |
Carbon Atomic Mass (amu) | 12.011 |
Carbon Atomic Number | 6 |
Carbon Chemical Element Symbol | C |
Carbon Covalent Radius (Å) | 0.76 |
Carbon Crystal Structure | Diamond Cubic (Diamond), Hexagonal (Graphite) |
Carbon Electronegativity (Pauling Scale) | 2.55 |
Carbon Electrons per Orbital Shell (inner most first) | 2, 4 |
Carbon Half-Life (Years) | N/A - Stable |
Carbon Lattice Parameter / Lattice Constant (Å) | Diamond a = 3.57, Graphite a = 2.46, c = 6.70 |
Carbon Number of Electron Orbital Shells | 2 |
Carbon Number of Electrons | 6 |
Carbon Number of Neutrons | 6 |
Carbon Number of Protons | 6 |
Carbon Periodic Table Series | Non-Metals |
Carbon Phase at 'Standard Temperature and Pressure' | Solid |
Carbon Stable Isotopes | C-12, C-13, C-14 |
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Electrical Properties of Carbon
Electrical Property (Units) | Value |
---|---|
Carbon Dielectric Constant at 'Standard Temperature and Pressure' | 5.7 – 5.9 (Diamond) |
Carbon Electrical Breakdown Voltage at Atmospheric Pressure (kV/mm) | 2000 (Diamond) |
Carbon Electrical Conductivity (S/m) | 1E-12 |
Carbon Electrical Resistivity at Room Temperature (25°C) (Ω·m) | 3.50E-05 (Graphite) or 1.00E+12 (Diamond) |
Carbon Magnetic Property | Diamagnetic |
Carbon Superconducting Transition Temperature (K) | 4 (At High Pressures) |
Carbon Temperature Coefficient of Resistance (°C⁻¹) | Negative Value (Graphite and Diamond) |
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Mechanical Properties of Carbon
Mechanical Property (Units) | Value |
---|---|
Carbon Compressive Strength (MPa) | 500 - 1500 |
Carbon Ductile to Brittle Transition Temperature (°C) | None (Brittle Always) |
Carbon Fatigue Limit (MPa) | 30 (Graphite) |
Carbon Fracture Toughness (MPa·√m) | 3 - 5 (Diamond), 2 - 4 (Graphite) |
Carbon Hardness Brinell | 10000 (Diamond), 1 - 3 (Graphite) |
Carbon Hardness Rockwell | 100 (HRA) (Diamond), 10 - 20 (HRB) (Graphite) |
Carbon Hardness Vickers | 10000 (Diamond), 5 - 10 (Graphite) |
Carbon Heat Deflection Temperature (°C) | N/A - Not a Polymer |
Carbon Modulus of Elasticity / Young's Modulus (GPa) | 1050 (Diamond), 11 (Graphite) |
Carbon Percent Elongation (%) | 0 (Diamond), 0 (Graphite) |
Carbon Poissons Ratio | 0.1 (Diamond), 0.16 (Graphite) |
Carbon Shear Modulus (GPa) | 478 (Diamond), 4.5 (Graphite) |
Carbon Shear Strength (MPa) | 5000 - 7000 (Diamond), 20 - 40 (Graphite) |
Carbon Ultimate Tensile Strength (MPa) | 2800 (Diamond), 20 - 30 (Graphite) |
Carbon Yield Strength (MPa) | Unknown |
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Physical Properties of Carbon
Physical Property (Units) | Value |
---|---|
Carbon Boiling Point at Atmospheric Pressure (°C) | Sublimates 3642 |
Carbon Chemical Composition (Element %) | C |
Carbon Cost ($/kg) | 45566 |
Carbon Density at 'Standard Temperature and Pressure' (kg/m3) | 2260 |
Carbon Glass Transition Temperature at Atmospheric Pressure (°C) | N/A |
Carbon Melting Point at Atmospheric Pressure (°C) | Sublimates 3642 |
Carbon Polymer Family | N/A - Not a Polymer |
Carbon Refractive Index | 2.42 (Diamond) |
Carbon Specific Gravity | 2.26 |
Carbon Viscosity at Melting Point (mPa·s) | Unknown |
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Thermal Properties of Carbon
Thermal Property (Units) | Value |
---|---|
Carbon Coefficient of Thermal Expansion (µm/m·K) | 7.1 (Graphite - Parallel), 25 (Graphite - Perpendicular), 1 (Diamond) |
Carbon Emissivity Coefficient | 0.7 - 0.8 (Graphite), 0.1 (Diamond) |
Carbon Specific Heat Capacity (J/kg·K) | 710 (Graphite), 519 (Diamond) |
Carbon Thermal Conductivity (W/m.K) | 270 (Graphite), 2350 (Diamond) |
Carbon Thermal Conductivity (BTU/h·ft·°F) | 156.11 (Graphite) , 1358.71 (Diamond) |
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