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Properties and Overview of Cobalt

Overview:

Image of Cobalt or Application Cobalt (Co) is a chemical element with the symbol Co and atomic number 27 on the periodic table. It is a transition metal in the middle of the periodic table and is known for its distinct bluish-gray appearance. Cobalt has been used for centuries, primarily as a pigment, but today, due to its unique physical and chemical properties, it plays a critical role in various industrial and technological applications. Physically, cobalt is a hard, lustrous metal with a high melting point of about 1,495°C and a boiling point of 2,930°C. It has a density of 8.90g/cm3, making it relatively heavy. Cobalt is ferromagnetic, which means it can be magnetized and retains its magnetism, similar to iron and nickel. This property is utilized to create high-performance magnets and magnetic materials. The metal exhibits good ductility, which allows it to be drawn into wires or hammered into sheets, although it is not as malleable as some other metals.
Chemically, Cobalt is relatively reactive and can exist in multiple oxidation states, the most common being +2 and +3. Cobalt compounds, particularly those in the +2 oxidation state, are stable and form various complexes with different ligands. One of Cobalt's notable chemical characteristics is its ability to form complex ions, which are used in coordination chemistry. Cobalt compounds are known for their vibrant colors; for example, Cobalt(II) chloride is blue in its hydrated form and pink when anhydrous. Cobalt also reacts with oxygen to form Cobalt oxide, which is often used in ceramics and as a catalyst in chemical reactions. Furthermore, Cobalt is resistant to corrosion and oxidation, which makes it useful in environments where durability and resistance to degradation are essential.
Regarding safety, cobalt and its compounds must be handled with care due to potential health risks. Prolonged exposure to Cobalt dust or fumes can cause respiratory problems, skin irritation, and, in severe cases, lung disease known as "hard metal lung disease" or pulmonary fibrosis. Cobalt is also considered a possible carcinogen when inhaled, especially in occupational settings where exposure levels may be higher. Ingestion of large amounts of cobalt can lead to Cobalt poisoning, which can affect the thyroid gland and cardiovascular system. Due to these risks, industries that use cobalt must adhere to strict safety guidelines, including proper ventilation, protective equipment, and regular health monitoring to ensure worker safety.


Production:

Cobalt is primarily a byproduct of nickel and copper mining since cobalt is typically found in ores alongside these metals. The most common Cobalt-bearing minerals include Cobaltite, erythrite, and skutterudite. The extraction process involves several stages, starting with the mining of ores, followed by concentration through flotation. The concentrated ore undergoes roasting to convert sulfides to oxides, which are then reduced using a blast furnace or electrolysis to produce metallic cobalt. In recent years, there has been an increasing focus on ethical sourcing and environmental sustainability in Cobalt production, mainly because significant deposits are located in politically unstable regions like the Democratic Republic of Congo, where mining practices can involve human rights concerns.


Applications:

Cobalt has a wide range of applications across various industries. One of its primary uses is producing high-strength alloys, particularly superalloys, which are essential in aerospace and turbine engines due to their strength and resistance to oxidation at high temperatures. Cobalt is also crucial in rechargeable batteries, particularly lithium-ion and lithium-cobalt oxide batteries, which are widely used in consumer electronics, electric vehicles, and portable devices. This has led to a surge in demand for cobalt in recent years, driven by the global push toward renewable energy and electric mobility.
In addition to these uses, cobalt plays an essential role in the medical field, particularly in radiotherapy for cancer treatment. Cobalt-60, a radioactive isotope of cobalt, is used in radiation therapy and as a source of gamma rays for sterilizing medical equipment and food irradiation. Cobalt compounds are also employed as catalysts in various chemical reactions, such as the Fischer-Tropsch process for converting carbon monoxide and hydrogen into hydrocarbons and in the hydroformylation of alkenes.


Summary:

Cobalt is a vital industrial metal with diverse applications ranging from advanced materials in high-performance alloys to essential components in batteries and medical devices. Its unique physical and chemical properties make it indispensable in many technological advancements, particularly in energy storage and renewable energy. However, the production and use of cobalt require careful management to mitigate environmental and health risks, emphasizing the need for sustainable practices and safety precautions.



See a comprehensive list of atomic, electrical, mechanical, physical and thermal properties for cobalt below:



Atomic Structure of Cobalt

Image of Cobalt Structure

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Atomic Properties of Cobalt

Atomic Property (Units) Value
Cobalt Atomic Electron Configuration [Ar] 3d74s2
Cobalt Atomic Mass (amu) 58.933
Cobalt Atomic Number 27
Cobalt Chemical Element Symbol Co
Cobalt Covalent Radius (Å) 1.26
Cobalt Crystal Structure Hexagonal Close-Packed (HCP)
Cobalt Electronegativity (Pauling Scale) 1.88
Cobalt Electrons per Orbital Shell (inner most first) 2, 8, 15, 2
Cobalt Half-Life (Years) N/A - Stable
Cobalt Lattice Parameter / Lattice Constant (Å) a = 2.51, c = 4.07
Cobalt Number of Electron Orbital Shells 4
Cobalt Number of Electrons 27
Cobalt Number of Neutrons 27
Cobalt Number of Protons 27
Cobalt Periodic Table Series Transition Metals
Cobalt Phase at 'Standard Temperature and Pressure' Solid
Cobalt Stable Isotopes Co-59

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Electrical Properties of Cobalt

Electrical Property (Units) Value
Cobalt Dielectric Constant at 'Standard Temperature and Pressure' Unknown
Cobalt Electrical Breakdown Voltage at Atmospheric Pressure (kV/mm) Unknown
Cobalt Electrical Conductivity (S/m) 1.7E+07
Cobalt Electrical Resistivity at Room Temperature (25°C) (Ω·m) 5.882E-08
Cobalt Magnetic Property Ferromagnetic
Cobalt Superconducting Transition Temperature (K) N/A - Not a Super Conductor
Cobalt Temperature Coefficient of Resistance (°C⁻¹) +0.0061 (6100 ppm/°C)

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Mechanical Properties of Cobalt

Mechanical Property (Units) Value
Cobalt Compressive Strength (MPa) 250 - 600
Cobalt Ductile to Brittle Transition Temperature (°C) -100
Cobalt Fatigue Limit (MPa) 180
Cobalt Fracture Toughness (MPa·√m) 55 - 115
Cobalt Hardness Brinell 150
Cobalt Hardness Rockwell 45 - 55 (HRC)
Cobalt Hardness Vickers 1043
Cobalt Heat Deflection Temperature (°C) N/A - Not a Polymer
Cobalt Modulus of Elasticity / Young's Modulus (GPa) 205 - 210
Cobalt Percent Elongation (%) 35
Cobalt Poissons Ratio 0.31
Cobalt Shear Modulus (GPa) 75
Cobalt Shear Strength (MPa) 100 - 150
Cobalt Ultimate Tensile Strength (MPa) 450 - 600
Cobalt Yield Strength (MPa) 180 - 310

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Physical Properties of Cobalt

Physical Property (Units) Value
Cobalt Boiling Point at Atmospheric Pressure (°C) 2927
Cobalt Chemical Composition (Element %) Co
Cobalt Cost ($/kg) 30
Cobalt Density at 'Standard Temperature and Pressure' (kg/m3) 8900
Cobalt Glass Transition Temperature at Atmospheric Pressure (°C) N/A
Cobalt Melting Point at Atmospheric Pressure (°C) 1495
Cobalt Polymer Family N/A - Not a Polymer
Cobalt Refractive Index Unknown
Cobalt Specific Gravity 8.9
Cobalt Viscosity at Melting Point (mPa·s) 4.43

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Thermal Properties of Cobalt

Thermal Property (Units) Value
Cobalt Coefficient of Thermal Expansion (µm/m·K) 13
Cobalt Emissivity Coefficient Unknown
Cobalt Specific Heat Capacity (J/kg·K) 421
Cobalt Thermal Conductivity (W/m.K) 100
Cobalt Thermal Conductivity (BTU/h·ft·°F) 57.82

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