Properties and Overview of Dysprosium
Overview:
Dysprosium (Dy) is a chemical element with the symbol Dy and atomic number 66. It is a member of the lanthanide series, a group of rare earth elements located in the f-block of the periodic table. Dysprosium is known for its high magnetic susceptibility. It is particularly valued for its ability to maintain magnetic properties at high temperatures, which makes it an essential material in various advanced technological applications. Physically, dysprosium is a soft, silver-white metal with a relatively high melting point of about 1,407°C and a boiling point of 2,567°C. It has a density of 8.54g/cm3, making it one of the denser rare earth metals. Dysprosium is relatively malleable and can be easily cut with a knife. It has a hexagonal close-packed crystal structure at room temperature, contributing to its mechanical properties. The metal is moderately reactive; it oxidizes slowly in the air and forms a layer of dysprosium oxide on its surface, which helps protect it from further corrosion. When exposed to higher temperatures, dysprosium reacts more readily with oxygen, water, and acids.
Chemically, dysprosium exhibits characteristics typical of the rare earth elements. Dysprosium compounds often exhibit interesting luminescent properties, making them useful in specific lighting and displays. The element also forms a variety of halides, sulfides, and other compounds. Dysprosium's unique electronic configuration, with half-filled 4f orbitals, gives it notable magnetic properties, including a high magnetic susceptibility. This makes dysprosium useful in applications that require materials with strong magnetic properties that can operate efficiently at elevated temperatures.
Safety considerations for dysprosium focus primarily on its chemical reactivity and potential toxicity. While dysprosium metal is relatively stable in air and not highly reactive at room temperature, it can form potentially hazardous compounds, such as dysprosium oxide or dysprosium chloride, that require careful handling. Dysprosium compounds are considered to have low to moderate toxicity if ingested or inhaled, and prolonged exposure to dysprosium dust or fumes can cause respiratory and skin irritation. In industrial settings, adequate ventilation and protective equipment, such as gloves and masks, are essential to prevent inhalation or contact with dysprosium dust or fumes. Because dysprosium is used in high-tech applications and is relatively rare, there is also an ongoing concern about the environmental impact of mining and refining rare earth elements, prompting efforts to improve recycling and sustainable sourcing practices.
Production:
The production of dysprosium primarily involves the extraction from rare earth minerals such as xenotime, monazite, and bastnaesite, typically mined in China, the United States, Australia, and other regions rich in rare earth deposits. The extraction process begins with the crushing and grinding of the ore, followed by a series of separation techniques, including solvent extraction and ion exchange, to isolate dysprosium from other rare earth elements. This is necessary because rare earth elements often occur together in nature and have similar chemical properties. After separation, dysprosium is converted into its oxide or chloride form and then reduced using a metallothermic reduction process, often involving calcium or other reactive metals, to produce metallic dysprosium.
Applications:
Dysprosium has several critical applications, especially in electronics, energy, and defense. One of its most significant uses is producing high-performance magnets, particularly neodymium-iron-boron (NdFeB) magnets. Dysprosium is added to these magnets to improve their resistance to demagnetization at high temperatures. It is essential in applications such as electric vehicle motors, wind turbine generators, and various types of sensors. This use is crucial for renewable energy technologies and the advancement of green technology initiatives. Dysprosium is also employed in nuclear reactors due to its high neutron absorption cross-section, making it an effective material for control rods that manage the rate of fission reactions. Additionally, dysprosium is used in certain types of laser materials, phosphorescent materials, and in the production of dosimeters for monitoring radiation exposure.
Summary:
Dysprosium is a vital rare earth element with unique properties that make it indispensable in various high-tech and energy-efficient applications. Its role in improving the performance and durability of magnets at high temperatures, along with its applications in nuclear energy and other advanced technologies, highlights its importance in modern industry. At the same time, the challenges associated with dysprosium's extraction, refining, and potential health and environmental impacts underscore the need for careful management and sustainable practices in its production and use.
See a comprehensive list of atomic, electrical, mechanical, physical and thermal properties for dysprosium below:
Atomic Structure of Dysprosium
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Atomic Properties of Dysprosium
Atomic Property (Units) | Value |
---|---|
Dysprosium Atomic Electron Configuration | [Xe] 4f106s2 |
Dysprosium Atomic Mass (amu) | 162.5 |
Dysprosium Atomic Number | 66 |
Dysprosium Chemical Element Symbol | Dy |
Dysprosium Covalent Radius (Å) | 1.92 |
Dysprosium Crystal Structure | Hexagonal Close-Packed (HCP) |
Dysprosium Electronegativity (Pauling Scale) | 1.22 |
Dysprosium Electrons per Orbital Shell (inner most first) | 2, 8, 18, 28, 8, 2 |
Dysprosium Half-Life (Years) | N/A - Stable |
Dysprosium Lattice Parameter / Lattice Constant (Å) | a = 3.59, c = 5.65 |
Dysprosium Number of Electron Orbital Shells | 6 |
Dysprosium Number of Electrons | 66 |
Dysprosium Number of Neutrons | 66 |
Dysprosium Number of Protons | 66 |
Dysprosium Periodic Table Series | Lanthanides |
Dysprosium Phase at 'Standard Temperature and Pressure' | Solid |
Dysprosium Stable Isotopes | Dy-164 |
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Electrical Properties of Dysprosium
Electrical Property (Units) | Value |
---|---|
Dysprosium Dielectric Constant at 'Standard Temperature and Pressure' | Unknown |
Dysprosium Electrical Breakdown Voltage at Atmospheric Pressure (kV/mm) | Unknown |
Dysprosium Electrical Conductivity (S/m) | 1E+06 |
Dysprosium Electrical Resistivity at Room Temperature (25°C) (Ω·m) | 1E-06 |
Dysprosium Magnetic Property | Ferromagnetic |
Dysprosium Superconducting Transition Temperature (K) | N/A - Not a Super Conductor |
Dysprosium Temperature Coefficient of Resistance (°C⁻¹) | +0.004 (4000 ppm/°C) |
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Mechanical Properties of Dysprosium
Mechanical Property (Units) | Value |
---|---|
Dysprosium Compressive Strength (MPa) | 150 |
Dysprosium Ductile to Brittle Transition Temperature (°C) | Unknown |
Dysprosium Fatigue Limit (MPa) | Unknown |
Dysprosium Fracture Toughness (MPa·√m) | 5 |
Dysprosium Hardness Brinell | 70 |
Dysprosium Hardness Rockwell | 25 (HRA) |
Dysprosium Hardness Vickers | 500 |
Dysprosium Heat Deflection Temperature (°C) | N/A - Not a Polymer |
Dysprosium Modulus of Elasticity / Young's Modulus (GPa) | 61.4 |
Dysprosium Percent Elongation (%) | 20 |
Dysprosium Poissons Ratio | 0.24 |
Dysprosium Shear Modulus (GPa) | 24.7 |
Dysprosium Shear Strength (MPa) | 120 |
Dysprosium Ultimate Tensile Strength (MPa) | 250 |
Dysprosium Yield Strength (MPa) | 210 |
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Physical Properties of Dysprosium
Physical Property (Units) | Value |
---|---|
Dysprosium Boiling Point at Atmospheric Pressure (°C) | 2567 |
Dysprosium Chemical Composition (Element %) | Dy |
Dysprosium Cost ($/kg) | 300 |
Dysprosium Density at 'Standard Temperature and Pressure' (kg/m3) | 8551 |
Dysprosium Glass Transition Temperature at Atmospheric Pressure (°C) | N/A |
Dysprosium Melting Point at Atmospheric Pressure (°C) | 1412 |
Dysprosium Polymer Family | N/A - Not a Polymer |
Dysprosium Refractive Index | Unknown |
Dysprosium Specific Gravity | 8.551 |
Dysprosium Viscosity at Melting Point (mPa·s) | Unknown |
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Thermal Properties of Dysprosium
Thermal Property (Units) | Value |
---|---|
Dysprosium Coefficient of Thermal Expansion (µm/m·K) | 9.9 |
Dysprosium Emissivity Coefficient | Unknown |
Dysprosium Specific Heat Capacity (J/kg·K) | 167 |
Dysprosium Thermal Conductivity (W/m.K) | 10.7 |
Dysprosium Thermal Conductivity (BTU/h·ft·°F) | 6.19 |
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