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Polymer Structure

Properties and Overview of PDMS (Polydimethylsiloxane)

Overview:

Image of PDMS or Application PDMS (Polydimethylsiloxane) is a versatile silicone-based polymer renowned for its flexibility, biocompatibility, and chemical stability. As one of the most widely used silicones, PDMS is a critical material in industries ranging from healthcare and electronics to construction and consumer goods. Its unique properties, including thermal stability, low surface energy, and resistance to water and chemicals, make it an indispensable material for a broad range of applications.


Production:

PDMS is synthesized by polymerizing dimethylsiloxane monomers in the presence of a catalyst. The polymer's structure consists of a silicon-oxygen backbone with organic methyl groups attached, giving it its characteristic flexibility and inertness. PDMS can be produced in various viscosities, from low-viscosity liquids to high-viscosity gums and elastomers, allowing customization to suit specific needs. It is often crosslinked or cured to create solid, durable materials with enhanced mechanical properties, such as silicone rubber or resins.


Applications:

Applications of PDMS are extensive and diverse due to its remarkable properties. PDMS is used for implants, prosthetics, and medical tubing in the medical field due to its biocompatibility and resistance to sterilization processes. It plays a crucial role in microfluidics, where its optical transparency and ease of molding allow for the creation of intricate lab-on-chip devices. In electronics, PDMS serves as an encapsulant and protective coating for sensitive components, offering insulation and protection from environmental factors. The construction industry relies on PDMS for sealants and adhesives that withstand temperature fluctuations and weathering. Additionally, it is used in personal care products, such as shampoos and lotions, due to its smooth texture and water-repellent properties. In industrial applications, PDMS is a key ingredient in lubricants, antifoaming agents, and release coatings.


Summary:

PDMS is a highly adaptable polymer with properties that make it a cornerstone material in modern technology and industry. Its flexibility, stability, and biocompatibility have established it as a reliable solution for applications ranging from medical devices to advanced electronics. As innovation continues to expand the possibilities of PDMS, it remains a vital material driving advancements in diverse fields.



See a comprehensive list of electrical, mechanical, physical and thermal properties for PDMS (Polydimethylsiloxane) below:



Electrical Properties of PDMS (Polydimethylsiloxane)

Electrical Property (Units) Value
PDMS (Polydimethylsiloxane) Dielectric Constant at 'Standard Temperature and Pressure' 2.7 to 3.3
PDMS (Polydimethylsiloxane) Electrical Breakdown Voltage at Atmospheric Pressure (kV/mm) ~20 to 25
PDMS (Polydimethylsiloxane) Electrical Conductivity (S/m) 1.00E-16 to 1.00E-14
PDMS (Polydimethylsiloxane) Electrical Resistivity at Room Temperature (25°C) (Ω·m) 1.00E+14 to 1.00E+16
PDMS (Polydimethylsiloxane) Magnetic Property N/A
PDMS (Polydimethylsiloxane) Superconducting Transition Temperature (K) N/A
PDMS (Polydimethylsiloxane) Temperature Coefficient of Resistance (°C⁻¹) Unknown

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Mechanical Properties of PDMS (Polydimethylsiloxane)

Mechanical Property (Units) Value
PDMS (Polydimethylsiloxane) Compressive Strength (MPa) ~10
PDMS (Polydimethylsiloxane) Ductile to Brittle Transition Temperature (°C) Unknown
PDMS (Polydimethylsiloxane) Fatigue Limit (MPa) Unknown
PDMS (Polydimethylsiloxane) Fracture Toughness (MPa·√m) Unknown
PDMS (Polydimethylsiloxane) Hardness Brinell Unknown
PDMS (Polydimethylsiloxane) Hardness Rockwell Unknown
PDMS (Polydimethylsiloxane) Hardness Vickers Unknown
PDMS (Polydimethylsiloxane) Heat Deflection Temperature (°C) ~50
PDMS (Polydimethylsiloxane) Modulus of Elasticity / Young's Modulus (GPa) 0.0002 to 0.0005
PDMS (Polydimethylsiloxane) Percent Elongation (%) 200
PDMS (Polydimethylsiloxane) Poissons Ratio 0.48 to 0.5
PDMS (Polydimethylsiloxane) Shear Modulus (GPa) ~0.00005
PDMS (Polydimethylsiloxane) Shear Strength (MPa) ~0.5
PDMS (Polydimethylsiloxane) Ultimate Tensile Strength (MPa) ~1
PDMS (Polydimethylsiloxane) Yield Strength (MPa) ~0.8

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Physical Properties of PDMS (Polydimethylsiloxane)

Physical Property (Units) Value
PDMS (Polydimethylsiloxane) Boiling Point at Atmospheric Pressure (°C) ~350
PDMS (Polydimethylsiloxane) Chemical Composition (Element %) (C2H6OSi)n
PDMS (Polydimethylsiloxane) Cost ($/kg) 5 to 15
PDMS (Polydimethylsiloxane) Density at 'Standard Temperature and Pressure' (kg/m3) 970 to 1020
PDMS (Polydimethylsiloxane) Glass Transition Temperature at Atmospheric Pressure (°C) -125
PDMS (Polydimethylsiloxane) Melting Point at Atmospheric Pressure (°C) ~50
PDMS (Polydimethylsiloxane) Polymer Family Thermosetting
PDMS (Polydimethylsiloxane) Refractive Index ~1.40
PDMS (Polydimethylsiloxane) Specific Gravity 0.97 to 1.02
PDMS (Polydimethylsiloxane) Viscosity at Melting Point (mPa·s) Unknown

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Thermal Properties of PDMS (Polydimethylsiloxane)

Thermal Property (Units) Value
PDMS (Polydimethylsiloxane) Coefficient of Thermal Expansion (µm/m·K) 300 to 400+
PDMS (Polydimethylsiloxane) Emissivity Coefficient ~0.9
PDMS (Polydimethylsiloxane) Specific Heat Capacity (J/kg·K) ~1460
PDMS (Polydimethylsiloxane) Thermal Conductivity (W/m.K) 0.18
PDMS (Polydimethylsiloxane) Thermal Conductivity (BTU/h·ft·°F) 0.10

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