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Polymer Structure

Properties and Overview of PMMA (Polymethyl Methacrylate)

Overview:

Image of PMMA or Application PMMA (Polymethyl Methacrylate) is a lightweight, durable thermoplastic renowned for its optical clarity and weather resistance. Often marketed under trade names like Plexiglas and Acrylite, PMMA is a transparent alternative to glass, offering similar clarity with more excellent impact resistance and significantly lower weight. These properties, combined with its versatility, make PMMA a popular material in industries ranging from construction and automotive to medical and consumer goods.


Production:

The production of PMMA involves polymerizing methyl methacrylate monomers using free radical polymerization techniques, often in bulk or suspension processes. This controlled production produces a polymer with high purity and consistent optical properties. PMMA can be processed through various methods, including extrusion, injection molding, and casting, allowing for the creation of sheets, rods, and complex shapes. Its ability to be easily machined, thermoformed, and polished further enhances its adaptability for diverse applications.


Applications:

PMMA's applications span various industries due to its clarity, durability, and weather resistance. In the construction sector, it is used for skylights, windows, and signage, where its transparency and UV resistance ensure long-term performance and aesthetic appeal. The automotive industry relies on PMMA for headlamp lenses, interior trims, and exterior panels, benefiting from its lightweight nature and ability to withstand impact. Due to its biocompatibility and clarity, PMMA is used for medical applications for intraocular lenses, orthopedic cement, and dental prosthetics. Additionally, PMMA is a key material for displays, lighting fixtures, and protective screens in electronics and consumer goods, where its optical and mechanical properties shine. Its artistic and decorative use in furniture, aquariums, and exhibition displays further underscores its versatility.


Summary:

Polymethyl Methacrylate is a highly adaptable and durable polymer that combines optical clarity, weather resistance, and ease of processing. Its ability to replace traditional glass in demanding applications highlights its importance in modern engineering and design. As innovation expands its potential uses, PMMA remains vital in industries seeking lightweight, transparent, and sustainable solutions for diverse challenges. Its enduring relevance ensures its place as a cornerstone material in architecture, healthcare, and technology.



See a comprehensive list of electrical, mechanical, physical and thermal properties for PMMA (Polymethyl Methacrylate) below:



Electrical Properties of PMMA (Polymethyl Methacrylate)

Electrical Property (Units) Value
PMMA (Polymethyl Methacrylate) Dielectric Constant at 'Standard Temperature and Pressure' 2.6 to 3.5
PMMA (Polymethyl Methacrylate) Electrical Breakdown Voltage at Atmospheric Pressure (kV/mm) ~20 to 25
PMMA (Polymethyl Methacrylate) Electrical Conductivity (S/m) 1.00E-16 to 1.00E-14
PMMA (Polymethyl Methacrylate) Electrical Resistivity at Room Temperature (25°C) (Ω·m) 1.00E+14 to 1.00E+16
PMMA (Polymethyl Methacrylate) Magnetic Property N/A
PMMA (Polymethyl Methacrylate) Superconducting Transition Temperature (K) N/A
PMMA (Polymethyl Methacrylate) Temperature Coefficient of Resistance (°C⁻¹) Unknown

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Mechanical Properties of PMMA (Polymethyl Methacrylate)

Mechanical Property (Units) Value
PMMA (Polymethyl Methacrylate) Compressive Strength (MPa) 90 to 130
PMMA (Polymethyl Methacrylate) Ductile to Brittle Transition Temperature (°C) 0
PMMA (Polymethyl Methacrylate) Fatigue Limit (MPa) 25
PMMA (Polymethyl Methacrylate) Fracture Toughness (MPa·√m) 1.5
PMMA (Polymethyl Methacrylate) Hardness Brinell 50
PMMA (Polymethyl Methacrylate) Hardness Rockwell 85 HRR
PMMA (Polymethyl Methacrylate) Hardness Vickers 70
PMMA (Polymethyl Methacrylate) Heat Deflection Temperature (°C) 85 to 105
PMMA (Polymethyl Methacrylate) Modulus of Elasticity / Young's Modulus (GPa) 3
PMMA (Polymethyl Methacrylate) Percent Elongation (%) 5
PMMA (Polymethyl Methacrylate) Poissons Ratio 0.4
PMMA (Polymethyl Methacrylate) Shear Modulus (GPa) 1.1
PMMA (Polymethyl Methacrylate) Shear Strength (MPa) 55
PMMA (Polymethyl Methacrylate) Ultimate Tensile Strength (MPa) 80
PMMA (Polymethyl Methacrylate) Yield Strength (MPa) 60

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Physical Properties of PMMA (Polymethyl Methacrylate)

Physical Property (Units) Value
PMMA (Polymethyl Methacrylate) Boiling Point at Atmospheric Pressure (°C) Decomposes
PMMA (Polymethyl Methacrylate) Chemical Composition (Element %) (C5H8O2)n
PMMA (Polymethyl Methacrylate) Cost ($/kg) 2 to 4
PMMA (Polymethyl Methacrylate) Density at 'Standard Temperature and Pressure' (kg/m3) 1180
PMMA (Polymethyl Methacrylate) Glass Transition Temperature at Atmospheric Pressure (°C) 105
PMMA (Polymethyl Methacrylate) Melting Point at Atmospheric Pressure (°C) 300
PMMA (Polymethyl Methacrylate) Polymer Family Thermoplastic
PMMA (Polymethyl Methacrylate) Refractive Index 1.49
PMMA (Polymethyl Methacrylate) Specific Gravity 1.18
PMMA (Polymethyl Methacrylate) Viscosity at Melting Point (mPa·s) Unknown

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Thermal Properties of PMMA (Polymethyl Methacrylate)

Thermal Property (Units) Value
PMMA (Polymethyl Methacrylate) Coefficient of Thermal Expansion (µm/m·K) 70 to 90
PMMA (Polymethyl Methacrylate) Emissivity Coefficient 0.9
PMMA (Polymethyl Methacrylate) Specific Heat Capacity (J/kg·K) 1470
PMMA (Polymethyl Methacrylate) Thermal Conductivity (W/m.K) 0.19
PMMA (Polymethyl Methacrylate) Thermal Conductivity (BTU/h·ft·°F) 0.11

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