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Polymer Structure

Properties and Overview of PPS (Polyphenylenesulphide)

Overview:

Image of PPS or Application PPS (Polyphenylenesulphide) is a high-performance engineering thermoplastic known for its exceptional thermal stability, chemical resistance, and mechanical strength. It is widely used in industries requiring materials that can withstand extreme temperatures, corrosive environments, and demanding mechanical stresses. PPS's unique combination of properties, including its inherent flame resistance and excellent dimensional stability, makes it a preferred choice for automotive, aerospace, electrical, and industrial applications.


Production:

The production of PPS typically involves the polymerization of p-dichlorobenzene and sodium sulfide under high-temperature conditions in a solvent medium. This process results in a semicrystalline polymer with a highly stable backbone consisting of alternating phenylene and sulfide units. PPS is often reinforced with fillers such as glass or carbon fibers to enhance its mechanical properties, including stiffness and wear resistance. The material can be processed through standard manufacturing methods like injection molding, extrusion, and compression molding, making it suitable for various applications.


Applications:

PPS's applications are diverse and span several industries due to its robust properties. In the automotive sector, PPS is used for under-the-hood components, such as coolant pumps, fuel system parts, and electrical connectors, where its resistance to heat, chemicals, and wear ensures long-term performance. In the aerospace sector, PPS finds applications in structural components and insulation materials, benefiting from its low weight, thermal stability, and flame resistance. The electrical and electronics industries rely on PPS for connectors, circuit boards, and housings, where its excellent dielectric properties and resistance to moisture and heat are critical. Additionally, PPS is used in industrial machinery for pumps, valves, and bearings, where its wear resistance and mechanical strength contribute to durability. Its use in filtration systems and chemical processing equipment underscores its ability to perform in harsh chemical environments.


Summary:

Polyphenylene Sulfide is a highly versatile and durable thermoplastic that combines exceptional thermal stability, chemical resistance, and mechanical strength. Its ability to withstand extreme conditions makes it an indispensable material in advanced engineering applications across multiple industries. As innovation continues pushing the boundaries of material science, PPS remains a key component in creating high-performance solutions that meet modern manufacturing and engineering challenges. Its enduring importance highlights its value as a cornerstone material in industrial and technological advancements.



See a comprehensive list of electrical, mechanical, physical and thermal properties for PPS (Polyphenylenesulphide) below:



Electrical Properties of PPS (Polyphenylenesulphide)

Electrical Property (Units) Value
PPS (Polyphenylenesulphide) Dielectric Constant at 'Standard Temperature and Pressure' 3.0 to 3.5
PPS (Polyphenylenesulphide) Electrical Breakdown Voltage at Atmospheric Pressure (kV/mm) ~25 to 30
PPS (Polyphenylenesulphide) Electrical Conductivity (S/m) 1.00E-15 to 1.00E-13
PPS (Polyphenylenesulphide) Electrical Resistivity at Room Temperature (25°C) (Ω·m) 1.00E+13 to 1.00E+15
PPS (Polyphenylenesulphide) Magnetic Property N/A
PPS (Polyphenylenesulphide) Superconducting Transition Temperature (K) N/A
PPS (Polyphenylenesulphide) Temperature Coefficient of Resistance (°C⁻¹) Unknown

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Mechanical Properties of PPS (Polyphenylenesulphide)

Mechanical Property (Units) Value
PPS (Polyphenylenesulphide) Compressive Strength (MPa) 80 to 150
PPS (Polyphenylenesulphide) Ductile to Brittle Transition Temperature (°C) ~0
PPS (Polyphenylenesulphide) Fatigue Limit (MPa) 30 to 40
PPS (Polyphenylenesulphide) Fracture Toughness (MPa·√m) 2.5 to 5.0
PPS (Polyphenylenesulphide) Hardness Brinell ~20
PPS (Polyphenylenesulphide) Hardness Rockwell 60 to 80 HRR
PPS (Polyphenylenesulphide) Hardness Vickers ~20
PPS (Polyphenylenesulphide) Heat Deflection Temperature (°C) 240 to 260
PPS (Polyphenylenesulphide) Modulus of Elasticity / Young's Modulus (GPa) 2.5 to 4.0
PPS (Polyphenylenesulphide) Percent Elongation (%) 5 to 15
PPS (Polyphenylenesulphide) Poissons Ratio 0.35 to 0.4
PPS (Polyphenylenesulphide) Shear Modulus (GPa) ~1.2
PPS (Polyphenylenesulphide) Shear Strength (MPa) 30 to 50
PPS (Polyphenylenesulphide) Ultimate Tensile Strength (MPa) 60 to 90
PPS (Polyphenylenesulphide) Yield Strength (MPa) 50 to 80

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Physical Properties of PPS (Polyphenylenesulphide)

Physical Property (Units) Value
PPS (Polyphenylenesulphide) Boiling Point at Atmospheric Pressure (°C) Decomposes
PPS (Polyphenylenesulphide) Chemical Composition (Element %) (C6H4S)n
PPS (Polyphenylenesulphide) Cost ($/kg) 10 to 15
PPS (Polyphenylenesulphide) Density at 'Standard Temperature and Pressure' (kg/m3) 1340 to 1380
PPS (Polyphenylenesulphide) Glass Transition Temperature at Atmospheric Pressure (°C) 85 to 100
PPS (Polyphenylenesulphide) Melting Point at Atmospheric Pressure (°C) ~285
PPS (Polyphenylenesulphide) Polymer Family Thermoplastic
PPS (Polyphenylenesulphide) Refractive Index 1.67 to 1.68
PPS (Polyphenylenesulphide) Specific Gravity 1.34 to 1.38
PPS (Polyphenylenesulphide) Viscosity at Melting Point (mPa·s) Unknown

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Thermal Properties of PPS (Polyphenylenesulphide)

Thermal Property (Units) Value
PPS (Polyphenylenesulphide) Coefficient of Thermal Expansion (µm/m·K) 10 to 30
PPS (Polyphenylenesulphide) Emissivity Coefficient ~0.9
PPS (Polyphenylenesulphide) Specific Heat Capacity (J/kg·K) 1000 to 1500
PPS (Polyphenylenesulphide) Thermal Conductivity (W/m.K) 0.3
PPS (Polyphenylenesulphide) Thermal Conductivity (BTU/h·ft·°F) 0.17

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