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Polymer Structure

Properties and Overview of PTFE (Polytetrafluoroethylene)

Overview:

Image of PTFE or Application PTFE (Polytetrafluoroethylene) is a high-performance fluoropolymer renowned for its exceptional chemical resistance, thermal stability, and low friction properties. Best known by the trade name Teflon, PTFE's unique characteristics make it indispensable in industries that require materials capable of withstanding extreme temperatures, corrosive environments, and demanding mechanical conditions. Its non-stick and electrically insulating properties further enhance its versatility across various applications.


Production:

The production of PTFE involves the polymerization of tetrafluoroethylene (TFE) monomers in a highly controlled environment. The process results in a polymer with a linear chain of carbon atoms surrounded by fluorine atoms, giving PTFE remarkable stability and resistance to almost all chemicals. PTFE is typically processed through compression molding and sintering techniques, as its high melting point and non-melt flow behavior limit traditional thermoplastic processing methods. Modified versions of PTFE, such as filled PTFE or expanded PTFE (ePTFE), are tailored for specific applications, improving properties like wear resistance or porosity.


Applications:

PTFE's applications are vast due to its unique properties. In the chemical and petrochemical industries, PTFE is used for seals, gaskets, and linings in equipment exposed to corrosive substances, where its chemical inertness ensures long-term reliability. PTFE is an insulating material for cables, connectors, and circuit boards in the electrical and electronics sectors due to its excellent dielectric properties and heat resistance. The automotive and aerospace industries rely on PTFE for components like bearings, bushings, and fuel system parts, benefiting from its low friction and ability to operate under extreme temperatures. In cookware and consumer goods, PTFE is widely known for its non-stick coatings on pans and utensils, ensuring easy cleaning and durability. Additionally, PTFE finds applications in medical devices, textiles, and industrial machinery, where its biocompatibility, hydrophobicity, and wear resistance play critical roles.


Summary:

Polytetrafluoroethylene is a remarkable fluoropolymer that combines chemical inertness, thermal stability, and low friction, making it a cornerstone material in modern engineering and manufacturing. Its ability to perform reliably under extreme conditions ensures its importance across diverse industries, from aerospace and automotive to healthcare and consumer products. As innovation continues to expand its applications and refine its properties, PTFE remains vital in addressing the challenges of modern technology and industrial demands. Its enduring significance underscores its role as a critical component in advanced engineering solutions.



See a comprehensive list of electrical, mechanical, physical and thermal properties for PTFE (Polytetrafluoroethylene) below:



Electrical Properties of PTFE (Polytetrafluoroethylene)

Electrical Property (Units) Value
PTFE (Polytetrafluoroethylene) Dielectric Constant at 'Standard Temperature and Pressure' 2.1 to 2.2
PTFE (Polytetrafluoroethylene) Electrical Breakdown Voltage at Atmospheric Pressure (kV/mm) ~60 to 120
PTFE (Polytetrafluoroethylene) Electrical Conductivity (S/m) 1.00E-20 to 1.00E-18
PTFE (Polytetrafluoroethylene) Electrical Resistivity at Room Temperature (25°C) (Ω·m) 1.00E+18 to 1.00E+20
PTFE (Polytetrafluoroethylene) Magnetic Property N/A
PTFE (Polytetrafluoroethylene) Superconducting Transition Temperature (K) N/A
PTFE (Polytetrafluoroethylene) Temperature Coefficient of Resistance (°C⁻¹) Unknown

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Mechanical Properties of PTFE (Polytetrafluoroethylene)

Mechanical Property (Units) Value
PTFE (Polytetrafluoroethylene) Compressive Strength (MPa) 10 to 15
PTFE (Polytetrafluoroethylene) Ductile to Brittle Transition Temperature (°C) - 130 to - 100
PTFE (Polytetrafluoroethylene) Fatigue Limit (MPa) 7
PTFE (Polytetrafluoroethylene) Fracture Toughness (MPa·√m) 1.5
PTFE (Polytetrafluoroethylene) Hardness Brinell 30
PTFE (Polytetrafluoroethylene) Hardness Rockwell 70 HRR
PTFE (Polytetrafluoroethylene) Hardness Vickers 50
PTFE (Polytetrafluoroethylene) Heat Deflection Temperature (°C) 50 to 100
PTFE (Polytetrafluoroethylene) Modulus of Elasticity / Young's Modulus (GPa) 0.5
PTFE (Polytetrafluoroethylene) Percent Elongation (%) 350
PTFE (Polytetrafluoroethylene) Poissons Ratio 0.46
PTFE (Polytetrafluoroethylene) Shear Modulus (GPa) 0.25
PTFE (Polytetrafluoroethylene) Shear Strength (MPa) 12
PTFE (Polytetrafluoroethylene) Ultimate Tensile Strength (MPa) 30
PTFE (Polytetrafluoroethylene) Yield Strength (MPa) 20

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Physical Properties of PTFE (Polytetrafluoroethylene)

Physical Property (Units) Value
PTFE (Polytetrafluoroethylene) Boiling Point at Atmospheric Pressure (°C) Decomposes
PTFE (Polytetrafluoroethylene) Chemical Composition (Element %) (C2F4)n
PTFE (Polytetrafluoroethylene) Cost ($/kg) 20 to 50
PTFE (Polytetrafluoroethylene) Density at 'Standard Temperature and Pressure' (kg/m3) 2150 to 2200
PTFE (Polytetrafluoroethylene) Glass Transition Temperature at Atmospheric Pressure (°C) -100
PTFE (Polytetrafluoroethylene) Melting Point at Atmospheric Pressure (°C) 330
PTFE (Polytetrafluoroethylene) Polymer Family Thermoplastic
PTFE (Polytetrafluoroethylene) Refractive Index 1.35
PTFE (Polytetrafluoroethylene) Specific Gravity 2.15 to 2.20
PTFE (Polytetrafluoroethylene) Viscosity at Melting Point (mPa·s) Unknown

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Thermal Properties of PTFE (Polytetrafluoroethylene)

Thermal Property (Units) Value
PTFE (Polytetrafluoroethylene) Coefficient of Thermal Expansion (µm/m·K) 10 to 20
PTFE (Polytetrafluoroethylene) Emissivity Coefficient 0.9
PTFE (Polytetrafluoroethylene) Specific Heat Capacity (J/kg·K) 1000
PTFE (Polytetrafluoroethylene) Thermal Conductivity (W/m.K) 0.25
PTFE (Polytetrafluoroethylene) Thermal Conductivity (BTU/h·ft·°F) 0.14

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