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Polymer Structure

Properties and Overview of PEI (Polyetherimide)

Overview:

Image of PEI or Application PEI (Polyetherimide) is a high-performance thermoplastic polymer renowned for its exceptional strength, thermal stability, and chemical resistance. Known under trade names like Ultem, PEI is widely used in industries requiring materials that can endure extreme conditions while maintaining excellent mechanical and electrical properties. Its unique properties, including flame resistance, dimensional stability, and biocompatibility, make it a go-to material for demanding engineering applications.


Production:

PEI is produced by polymerizing aromatic bisphenol monomers and anhydrides, forming a rigid molecular structure with imide linkages. This structure gives PEI high heat resistance, allowing it to operate in continuous temperatures exceeding 170°C without degradation. It can be processed using techniques like injection molding, extrusion, and thermoforming, which enable manufacturers to produce complex and precise components. PEI is often modified with glass or carbon fiber fillers to enhance properties like stiffness, strength, and thermal conductivity.


Applications:

PEI's applications span various industries due to its outstanding thermal and mechanical properties. In the aerospace sector, it is used for lightweight structural components, insulation materials, and cabin interiors, where its flame resistance and high strength-to-weight ratio are critical. The medical field employs PEI for sterilizable devices, surgical instruments, and diagnostic equipment, taking advantage of its biocompatibility and resistance to repeated autoclaving. PEI is used for connectors, printed circuit board holders, and insulating electronics components due to its dielectric properties and ability to withstand high operating temperatures. The automotive industry utilizes PEI for under-the-hood components, lighting systems, and sensor housings, where durability and thermal resistance are essential. Additionally, PEI finds applications in 3D printing for creating strong, high-temperature-resistant prototypes and functional parts.


Summary:

Polyetherimide is a highly versatile thermoplastic polymer that combines exceptional thermal stability, strength, and chemical resistance. Its ability to perform in extreme environments makes it an essential material in aerospace, medical, electronics, and automotive industries. As advancements in technology and material science continue, PEI remains a critical choice for applications requiring high-performance materials that deliver reliability and innovation.



See a comprehensive list of electrical, mechanical, physical and thermal properties for PEI (Polyetherimide) below:



Electrical Properties of PEI (Polyetherimide)

Electrical Property (Units) Value
PEI (Polyetherimide) Dielectric Constant at 'Standard Temperature and Pressure' 3.1 to 3.9
PEI (Polyetherimide) Electrical Breakdown Voltage at Atmospheric Pressure (kV/mm) ~20 to 30
PEI (Polyetherimide) Electrical Conductivity (S/m) 1.00E-15 to 1.00E-13
PEI (Polyetherimide) Electrical Resistivity at Room Temperature (25°C) (Ω·m) 1.00E+13 to 1.00E+15
PEI (Polyetherimide) Magnetic Property N/A
PEI (Polyetherimide) Superconducting Transition Temperature (K) N/A
PEI (Polyetherimide) Temperature Coefficient of Resistance (°C⁻¹) Unknown

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Mechanical Properties of PEI (Polyetherimide)

Mechanical Property (Units) Value
PEI (Polyetherimide) Compressive Strength (MPa) 85 to 130
PEI (Polyetherimide) Ductile to Brittle Transition Temperature (°C) - 70 to - 60
PEI (Polyetherimide) Fatigue Limit (MPa) 45
PEI (Polyetherimide) Fracture Toughness (MPa·√m) 3
PEI (Polyetherimide) Hardness Brinell 80
PEI (Polyetherimide) Hardness Rockwell 120 HRR
PEI (Polyetherimide) Hardness Vickers 120
PEI (Polyetherimide) Heat Deflection Temperature (°C) 200 to 215
PEI (Polyetherimide) Modulus of Elasticity / Young's Modulus (GPa) 3.4
PEI (Polyetherimide) Percent Elongation (%) 20
PEI (Polyetherimide) Poissons Ratio 0.36
PEI (Polyetherimide) Shear Modulus (GPa) 1.2
PEI (Polyetherimide) Shear Strength (MPa) 65
PEI (Polyetherimide) Ultimate Tensile Strength (MPa) 115
PEI (Polyetherimide) Yield Strength (MPa) 100

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Physical Properties of PEI (Polyetherimide)

Physical Property (Units) Value
PEI (Polyetherimide) Boiling Point at Atmospheric Pressure (°C) Decomposes
PEI (Polyetherimide) Chemical Composition (Element %) (C37H24O6N2)n
PEI (Polyetherimide) Cost ($/kg) 30 to 40
PEI (Polyetherimide) Density at 'Standard Temperature and Pressure' (kg/m3) 1270
PEI (Polyetherimide) Glass Transition Temperature at Atmospheric Pressure (°C) 215
PEI (Polyetherimide) Melting Point at Atmospheric Pressure (°C) 550
PEI (Polyetherimide) Polymer Family Thermoplastic
PEI (Polyetherimide) Refractive Index 1.66
PEI (Polyetherimide) Specific Gravity 1.27
PEI (Polyetherimide) Viscosity at Melting Point (mPa·s) Unknown

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Thermal Properties of PEI (Polyetherimide)

Thermal Property (Units) Value
PEI (Polyetherimide) Coefficient of Thermal Expansion (µm/m·K) 30 to 50
PEI (Polyetherimide) Emissivity Coefficient 0.85 to 0.9
PEI (Polyetherimide) Specific Heat Capacity (J/kg·K) 1100
PEI (Polyetherimide) Thermal Conductivity (W/m.K) 0.22
PEI (Polyetherimide) Thermal Conductivity (BTU/h·ft·°F) 0.13

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