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Polymer Structure

Properties and Overview of PEKK (Polyetherketoneketone)

Overview:

Image of PEKK or Application PEKK (Polyetherketoneketone) is a high-performance thermoplastic polymer recognized for its exceptional strength, chemical resistance, and thermal stability. As a polyaryletherketone (PAEK) family member, PEKK stands out due to its unique balance of properties, including high mechanical performance, resistance to harsh environments, and excellent processability. These characteristics make it a preferred material in aerospace, automotive, medical, and energy industries, where reliability and durability under extreme conditions are critical.


Production:

The production of PEKK involves the step-growth polymerization of monomers such as terephthalic acid and difluorobenzophenone. Its molecular structure, featuring ketone and ether linkages, contributes to its rigidity, high melting point, and chemical stability. PEKK differs from other PAEKs like PEEK due to its tunable crystallinity; manufacturers can adjust its processing and performance characteristics to meet specific application needs. It is compatible with various fabrication methods, including injection molding, extrusion, compression molding, and additive manufacturing, allowing for versatile use in complex and demanding designs.


Applications:

PEKK's applications span many industries due to its ability to withstand extreme conditions. In the aerospace sector, it is used for structural components, brackets, and insulation parts, where its lightweight nature and resistance to high temperatures and chemical exposure ensure performance and longevity. The medical field utilizes PEKK for implants, dental devices, and surgical instruments, benefiting from its biocompatibility and resistance to sterilization processes. In the automotive industry, PEKK is employed for engine components, electrical housings, and fuel system parts, where its durability and thermal stability are crucial. Additionally, PEKK is used in oil and gas exploration and production equipment in the energy sector, where it provides mechanical strength and corrosion resistance under high pressures and temperatures.


Summary:

Polyether Ketone Ketone is a high-performance polymer that combines strength, chemical resistance, and thermal stability, making it indispensable in industries that demand reliability under extreme conditions. Its versatility and ability to meet stringent performance requirements ensure its ongoing importance in engineering and manufacturing. As industries evolve and the demand for advanced materials grows, PEKK is vital in enabling innovation and delivering high-performance solutions across diverse applications.



See a comprehensive list of electrical, mechanical, physical and thermal properties for PEKK (Polyetherketoneketone) below:



Electrical Properties of PEKK (Polyetherketoneketone)

Electrical Property (Units) Value
PEKK (Polyetherketoneketone) Dielectric Constant at 'Standard Temperature and Pressure' 3.4
PEKK (Polyetherketoneketone) Electrical Breakdown Voltage at Atmospheric Pressure (kV/mm) ~18 to 22
PEKK (Polyetherketoneketone) Electrical Conductivity (S/m) 1.00E-14 to 1.00E-13
PEKK (Polyetherketoneketone) Electrical Resistivity at Room Temperature (25°C) (Ω·m) 1.00E+13 to 1.00E+14
PEKK (Polyetherketoneketone) Magnetic Property N/A
PEKK (Polyetherketoneketone) Superconducting Transition Temperature (K) N/A
PEKK (Polyetherketoneketone) Temperature Coefficient of Resistance (°C⁻¹) Unknown

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Mechanical Properties of PEKK (Polyetherketoneketone)

Mechanical Property (Units) Value
PEKK (Polyetherketoneketone) Compressive Strength (MPa) 110 to 160
PEKK (Polyetherketoneketone) Ductile to Brittle Transition Temperature (°C) - 100 to - 60
PEKK (Polyetherketoneketone) Fatigue Limit (MPa) 55
PEKK (Polyetherketoneketone) Fracture Toughness (MPa·√m) 4.5
PEKK (Polyetherketoneketone) Hardness Brinell 85
PEKK (Polyetherketoneketone) Hardness Rockwell 125 HRR
PEKK (Polyetherketoneketone) Hardness Vickers 130
PEKK (Polyetherketoneketone) Heat Deflection Temperature (°C) 170 to 220
PEKK (Polyetherketoneketone) Modulus of Elasticity / Young's Modulus (GPa) 3.8
PEKK (Polyetherketoneketone) Percent Elongation (%) 30
PEKK (Polyetherketoneketone) Poissons Ratio 0.36
PEKK (Polyetherketoneketone) Shear Modulus (GPa) 1.5
PEKK (Polyetherketoneketone) Shear Strength (MPa) 95
PEKK (Polyetherketoneketone) Ultimate Tensile Strength (MPa) 95
PEKK (Polyetherketoneketone) Yield Strength (MPa) 80

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Physical Properties of PEKK (Polyetherketoneketone)

Physical Property (Units) Value
PEKK (Polyetherketoneketone) Boiling Point at Atmospheric Pressure (°C) Decomposes
PEKK (Polyetherketoneketone) Chemical Composition (Element %) (C14H10O3)n
PEKK (Polyetherketoneketone) Cost ($/kg) 80 to 120
PEKK (Polyetherketoneketone) Density at 'Standard Temperature and Pressure' (kg/m3) 1300 to 1310
PEKK (Polyetherketoneketone) Glass Transition Temperature at Atmospheric Pressure (°C) 155
PEKK (Polyetherketoneketone) Melting Point at Atmospheric Pressure (°C) 305
PEKK (Polyetherketoneketone) Polymer Family Thermoplastic
PEKK (Polyetherketoneketone) Refractive Index 1.67
PEKK (Polyetherketoneketone) Specific Gravity 1.30 to 1.31
PEKK (Polyetherketoneketone) Viscosity at Melting Point (mPa·s) Unknown

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Thermal Properties of PEKK (Polyetherketoneketone)

Thermal Property (Units) Value
PEKK (Polyetherketoneketone) Coefficient of Thermal Expansion (µm/m·K) 10 to 50
PEKK (Polyetherketoneketone) Emissivity Coefficient 0.85 to 0.9
PEKK (Polyetherketoneketone) Specific Heat Capacity (J/kg·K) 1000
PEKK (Polyetherketoneketone) Thermal Conductivity (W/m.K) 0.25
PEKK (Polyetherketoneketone) Thermal Conductivity (BTU/h·ft·°F) 0.14

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