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Polymer Structure

Properties and Overview of PS (Polystyrene)

Overview:

Image of PS or Application PS (Polystyrene) is a widely used thermoplastic polymer recognized for its lightweight, rigidity, and ease of processing. Its versatility and cost-effectiveness have made it one of the most popular plastics in the world, serving industries such as packaging, construction, electronics, and consumer goods. Polystyrene's ability to be produced in various forms, including solid, foam, and film, enhances its adaptability across multiple applications.


Production:

The production of polystyrene involves the polymerization of styrene monomers, typically using free radical polymerization techniques. This process results in a clear, brittle material that can be modified to suit specific requirements. General-purpose polystyrene (GPPS) is clear and rigid, while high-impact polystyrene (HIPS) is blended with rubber to improve its toughness and impact resistance. Expanded polystyrene (EPS) and extruded polystyrene (XPS) are foam forms known for their excellent insulating properties and lightweight nature. Polystyrene can be processed through injection molding, extrusion, thermoforming, and other conventional methods, efficiently manufacturing diverse products.


Applications:

Polystyrene's applications are extensive due to its unique combination of properties. In the packaging industry, it is widely used for disposable containers, cups, and food trays, where its lightweight nature and ease of molding provide cost-effective solutions. Expanded polystyrene is utilized in construction as an insulating material for walls, roofs, and foundations, offering excellent thermal performance and energy efficiency. The electronics industry employs polystyrene for housings, insulation, and protective casings, benefiting from its rigidity and dimensional stability. Additionally, polystyrene is used in consumer products such as toys, household items, and furniture thanks to its versatility and affordability. EPS foam is also prominent in protective packaging for fragile goods and as a core material in lightweight structural designs.


Summary:

Polystyrene is a versatile and economical polymer that has become fundamental in modern industry and daily life. Its ability to meet diverse application needs and its ease of production and processing ensures its continued relevance across packaging, construction, and consumer markets. As industries focus on sustainability, efforts to recycle and innovate with polystyrene will further enhance its role in addressing the challenges of contemporary manufacturing and environmental considerations. Its enduring importance underscores its value as a cornerstone material in global production.



See a comprehensive list of electrical, mechanical, physical and thermal properties for PS (Polystyrene) below:



Electrical Properties of PS (Polystyrene)

Electrical Property (Units) Value
PS (Polystyrene) Dielectric Constant at 'Standard Temperature and Pressure' 2.4 to 2.7
PS (Polystyrene) Electrical Breakdown Voltage at Atmospheric Pressure (kV/mm) ~20 to 30
PS (Polystyrene) Electrical Conductivity (S/m) 1.00E-18 to 1.00E-16
PS (Polystyrene) Electrical Resistivity at Room Temperature (25°C) (Ω·m) 1.00E+16 to 1.00E+18
PS (Polystyrene) Magnetic Property N/A
PS (Polystyrene) Superconducting Transition Temperature (K) N/A
PS (Polystyrene) Temperature Coefficient of Resistance (°C⁻¹) Unknown

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Mechanical Properties of PS (Polystyrene)

Mechanical Property (Units) Value
PS (Polystyrene) Compressive Strength (MPa) 30 to 60
PS (Polystyrene) Ductile to Brittle Transition Temperature (°C) ~10
PS (Polystyrene) Fatigue Limit (MPa) Unknown
PS (Polystyrene) Fracture Toughness (MPa·√m) 1.0 to 2.0
PS (Polystyrene) Hardness Brinell ~10
PS (Polystyrene) Hardness Rockwell 40 to 60 HRR
PS (Polystyrene) Hardness Vickers ~10
PS (Polystyrene) Heat Deflection Temperature (°C) 80 to 100
PS (Polystyrene) Modulus of Elasticity / Young's Modulus (GPa) 3.0 to 3.5
PS (Polystyrene) Percent Elongation (%) 1 to 2
PS (Polystyrene) Poissons Ratio 0.33
PS (Polystyrene) Shear Modulus (GPa) ~1.2
PS (Polystyrene) Shear Strength (MPa) 30 to 40
PS (Polystyrene) Ultimate Tensile Strength (MPa) 40 to 60
PS (Polystyrene) Yield Strength (MPa) 30 to 50

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Physical Properties of PS (Polystyrene)

Physical Property (Units) Value
PS (Polystyrene) Boiling Point at Atmospheric Pressure (°C) Decomposes
PS (Polystyrene) Chemical Composition (Element %) (C8H8)n
PS (Polystyrene) Cost ($/kg) 2 to 4
PS (Polystyrene) Density at 'Standard Temperature and Pressure' (kg/m3) 1040 to 1060
PS (Polystyrene) Glass Transition Temperature at Atmospheric Pressure (°C) 90 to 100
PS (Polystyrene) Melting Point at Atmospheric Pressure (°C) ~240
PS (Polystyrene) Polymer Family Thermoplastic
PS (Polystyrene) Refractive Index 1.59 to 1.60
PS (Polystyrene) Specific Gravity 1.04 to 1.06
PS (Polystyrene) Viscosity at Melting Point (mPa·s) Unknown

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Thermal Properties of PS (Polystyrene)

Thermal Property (Units) Value
PS (Polystyrene) Coefficient of Thermal Expansion (µm/m·K) 100 to 150
PS (Polystyrene) Emissivity Coefficient ~0.95
PS (Polystyrene) Specific Heat Capacity (J/kg·K) 1200 to 1500
PS (Polystyrene) Thermal Conductivity (W/m.K) 0.08
PS (Polystyrene) Thermal Conductivity (BTU/h·ft·°F) 0.05

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